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Go to Editorial ManagerThe growing demand for energy, coupled with the continued dominance of fossil fuels as the primary energy source, necessitates eco-friendly technologies that simultaneously enhance oil recovery (EOR) and reduce the impact of their emissions. Only one task, which is the CO2-EOR project, can combine these two sustainable development goals. Further, employing green nanotechnology, including nanoparticles and nanofluids, ensures a sustainable approach to controlling and enhancing rock wettability, thereby enhancing hydrocarbon production and carbon storage. However, the performance of nanofluids in subsurface formations is limited by the stability of these nano-dispersions at the harsh conditions of reservoirs. This work thus synthesizes silica nanoparticles from waste bentonite as a green source and modifies the surface properties with a silane group to formulate a stable nanofluid for subsurface applications. The produced nanoparticles were characterized via Fourier Transform Infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), zetasizer, and dynamic light scattering (DLS). Moreover, the efficiency of nanoparticles as wettability-modifying agents was studied using contact angle and spontaneous imbibition tests. FTIR measurements confirmed the presence of silane on the surface of hybrid silica nanoparticles, as indicated within the Wavenumber 2950 cm-1. Moreover, XRD measurements revealed that hybrid nanoparticles showed lower noise than pure ones. Results also showed that silane-treated nanoparticles (hybrid) are more tolerant to high salinity (≥ 0.5wt% brine), and green-synthesized nanoparticles have a drastic ability to invert the wettability of oil-wet surfaces (θ≥123°) to water-wet (θ ≤ 28°) at ambient conditions and also reduce the contact angle from 175° to 68°) at CO2-EOR conditions. The study concludes that these green nanofluids are highly efficient for EOR and carbon geosequestration projects when properly formulated.
The objective of the current study is to determine the accuracy of a computational model that has been developed to simulate polyurethane foaming reactions by comparing its results with experimental findings on the system using both physical and chemical blowing agents. There was high concordance between the model outputs and the laboratory results in regard to the temporal development of reaction temperature as well as the resulting foam density, both of which were highly faithful recreations. The discussion provided further information about the optimization of the performance of cyclohexane, particularly when used in synergy with chemically active blowing agents, which speed up foaming. Besides, the polymerization dynamics were contained in the simulation, thus providing rich information on the structural changes that occur during the foaming process. Taken together, the results present a strong basis for the process performance optimization, as well as the predictive modeling of the blowing agent behavior. In the future, it will involve expanding the simulation model to include a wider range of agents, reaction mechanisms, and kinetics.
50W monocrystalline silicon solar module performance is tested with experimental measurements conducted at Baghdad city /Al-Jaderia (33.26 N, 44.21E). Solar irradiance striking is subjected to more losses which after the experiments conducted resulted approximately in 15% of the total energy which is converted into electric power energy. To study the effect of temperature variations on solar performance, solar irradiance must be kept constant and vice versa. Therefore, to have of the temperature range and for more accuracy, the measurements was done for tested module with three solar radiations levels; 500, 750 and 1000 W/m2. The maximum value of power (Pmax) at solar radiation intensity 1000W/m² was 46.34 W on January 2025 at cell temperature 24.1 oC, with the corresponding the maximum open voltage, and open circuit current 18.28 V, and 2.944 A respectively. The highest value of efficiency was 13.5 % January 2025 at solar radiation 500W/m². Consequently, The minimum value of power (Pmax) at solar radiation intensity 500W/m² was 27.54 W on October 2024 at cell temperature 40.5 oC, with the corresponding the maximum open voltage, and open circuit current 18.01 V, and 1.752 A respectively. The lowest value of efficiency was 6.9 % October 2024 at solar radiation 1000W/m². In general, the results showed slightly decrease in short circuit current with temperature increasing. With temperatures change great influence on the output voltage especially on open circuit voltage while very small decrease in the output current has been noticed.